导热橡胶在航空、航天、电子、电器领域有着广泛的应用前景.把碳纳米管填充到橡胶中,渴望获得具有优良导热性能的橡胶复合材料已成为材料领域研究的热点.本文综述了填充型导热橡胶的实验研究现状、导热橡胶的导热机理、导热模型;重点论述了碳纳米管的结构与改性、碳纳米管填充橡胶的导热性能的实验研究及理论研究进展;最后指出碳纳米管的独特结构和优异性能使其作为橡胶复合材料导热增强组分在理论上具有明显优势,但其复合材料的热物性研究仍存在一些问题有待解决;如何降低界面热阻、增加碳纳米管取向等将是提高碳纳米管/橡胶复合材料导热性能的重要解决途径.
参考文献
| [1] | 王振华 .橡胶纳米增强机理及新型增强导热橡胶复合材料的制备、结构与性能研究[D].北京化工大学,2010. |
| [2] | 姜靖雯;彭峰.碳纳米管应用研究现状与进展[J].材料科学与工程学报,2003(3):464-468. |
| [3] | 王泽鹏;邱克;张世誉.碳纳米管/橡胶复合材料的研究进展及热物性研究展望[J].弹性体,2008(6):61-65. |
| [4] | 王丹勇;陈以蔚;李树虎;秦贞明;徐井利;刘俊聪.碳纳米管/连续纤维增强树脂基复合材料力学性能设计[J].材料科学与工程学报,2013(1):153-158. |
| [5] | 陶新永 .新型一维碳纳米材料的热CVD法合成及性能研究[D].浙江大学,2007. |
| [6] | 宫世云;张文龙;谢刚;Bandyopadhyay Sri;赵洪.纤维素硝酸酯在MWCNTs/PMMA复合体系中的助分散作用[J].材料科学与工程学报,2013(1):11-16. |
| [7] | 孔丽芬;张银华;徐珊.导热硅橡胶的研究进展[J].粘接,2009(6):64-66. |
| [8] | Zhou WY;Wang CF;An QL;Ou HY.Thermal properties of heat conductive silicone rubber filled with hybrid fillers[J].Journal of Composite Materials,20082(2):173-187. |
| [9] | 马琳 .碳纳米管/三元乙丙橡胶复合材料导热性能及力学性能的实验研究[D].青岛科技大学,2013. |
| [10] | 李侃社;王琪.聚合物复合材料导热性能的研究[J].高分子材料科学与工程,2002(4):10-15. |
| [11] | Zhou WY;Qi SH;Tu CC;Zhao HZ;Wang CF;Kou JL.Effect of the particle size of Al2O3 on the properties of filled heat-conductive silicone rubber[J].Journal of Applied Polymer Science,20072(2):1312-1318. |
| [12] | Luiz Meyer;Shesha Jayaram;Edward A. Cherney.Thermal Conductivity of Filled Silicone Rubber and its Relationship to Erosion Resistance in the Inclined Plane Test[J].IEEE transactions on dielectrics and electrical insulation: A publication of the IEEE Dielectrics and Electrical Insulation Society,20044(4):620-630. |
| [13] | Sim LC;Ramanan SR;Ismail H;Seetharamu KN;Goh TJ.Thermal characterization of Al2O3 and ZnO reinforced silicone rubber as thermal pads for heat dissipation purposes[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,20051/2(1/2):155-165. |
| [14] | Zhen-Hua Wang;Yong-Lai Lu;Jun Liu;Zhi-Min Dang;Li-Qun Zhang;Weimin Wang.Preparation of nanoalumina/EPDM composites with good performance in thermal conductivity and mechanical properties[J].Polymers for advanced technologies,201112(12):2302-2310. |
| [15] | 翟俊学;陈锋;董凌波;张萍;赵树高.导热填料对NR/BR硫化胶的生热和导热的影响[J].特种橡胶制品,2009(6):14-18. |
| [16] | 潘大海;刘梅;孟岩;齐士成.导热绝缘室温硫化硅橡胶的研制[J].橡胶工业,2004(9):534-536. |
| [17] | Wang Q.;Gao W.;Xie ZM..Highly thermally conductive room-temperature-vulcanized silicone rubber and silicone grease[J].Journal of Applied Polymer Science,20039(9):2397-2399. |
| [18] | 涂春潮;齐暑华;周文英;赵红振;吴波.氮化硼填充MVQ制备导热橡胶的研究[J].橡胶工业,2007(2):93-95. |
| [19] | Kemaloglu, S;Ozkoc, G;Aytac, A.Properties of thermally conductive micro and nano size boron nitride reinforced silicon rubber composites[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,20101/2(1/2):40-47. |
| [20] | El-Tantawy F..New double negative and positives temperature coefficients of conductive EPDM rubber TiC ceramic composites[J].European Polymer Journal,20023(3):567-577. |
| [21] | Gwaily SE.;Badawy MM.;Hassan HH.;Madani M..Natural rubber composites as thermal neutron radiation shields I. B4C/NR composites[J].Polymer Testing,20022(2):129-133. |
| [22] | Weng, G.;Huang, G.;Qu, L.;Zhang, P.;Nie, Y.;Wu, J..Natural rubber with low heat generation achieved by the inclusion of boron carbide[J].Journal of Applied Polymer Science,20104(4):2050-2055. |
| [23] | 周湘文;朱跃峰;宋鹏程;刘长洪;熊国平;梁吉;董建令;于溯源.碳纳米管/粉末丁苯橡胶复合材料的热学性能[J].高分子材料科学与工程,2009(2):62-65. |
| [24] | Das A;Stockelhuber KW;Jurk R;Saphiannikova M;Fritzsche J;Lorenz H;Kluppel M;Heinrich G.Modified and unmodified multiwalled carbon nanotubes in high performance solution-styrene-butadiene and butadiene rubber blends[J].Polymer: The International Journal for the Science and Technology of Polymers,200824(24):5276-5283. |
| [25] | Hong, J.;Lee, J.;Jung, D.;Shim, S.E..Thermal and electrical conduction behavior of alumina and multiwalled carbon nanotube incorporated poly(dimethyl siloxane)[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,20111/2(1/2):34-39. |
| [26] | 何强;卢咏来;陈琪;刘宇;张立群.碳纳米管/Al2O3/硅橡胶导热复合材料结构和性能的研究[J].特种橡胶制品,2009(2):1-6. |
| [27] | Mansour, SA;Al-Ghoury, ME;Shalaan, E;El Eraki, MHI;Abdel-Bary, EM.Thermal Properties of Graphite-Loaded Nitrile Rubber/Poly(vinyl chloride) Blends[J].Journal of Applied Polymer Science,20106(6):3171-3177. |
| [28] | Vinod VS.;Varghese S.;Kuriakose B..Aluminum powder filled nitrile rubber composites[J].Journal of Applied Polymer Science,20045(5):3156-3161. |
| [29] | 冯娟娟 .碳纳米管定向填充天然橡胶导热性能的实验研究[D].青岛科技大学,2014. |
| [30] | Yoong Ahm Kim;Takuaya Hayashi;Morinobu Endo.Fabrication of Aligned Carbon Nanotube-Filled Rubber Composite[J].Scripta materialia,20061(1):31-35. |
| [31] | Hua Huang;Changhong Liu;Yang Wu;Shoushan Fan.Aligned Carbon Nanotube Composite Films for Thermal Management[J].Advanced Materials,200513(13):1652-1656. |
| [32] | Zhidong Han;Alberto Fina.Thermal conductivity of carbon nanotubes and their polymer nanocomposites: A review[J].Progress in Polymer Science,20117(7):914-944. |
| [33] | 涂春潮;齐暑华;周文英;赵红振;吴波.填充型导热橡胶研究进展[J].合成橡胶工业,2006(04):305-309. |
| [34] | Okamoto Shoji;Ishida Hatsuo.New theoretical equation for thermal conductivity of two-phase systems[J].Journal of Applied Polymer Science,199913(13):1689-1697. |
| [35] | 唐明明;容敏智;马传国;章明秋;叶建荣.Al2O3的表面处理及粒子尺寸对SBR导热橡胶性能的影响[J].合成橡胶工业,2003(2):104-107. |
| [36] | 闫刚;魏伯荣;杨海涛;肖琰.聚合物基复合材料导热模型及其研究进展[J].玻璃钢/复合材料,2006(3):50-52,49. |
| [37] | J. K. Carson;S. J. Lovatt;D. J. Tanner;A. C. Cleland.An analysis of the influence of material structure on the effective thermal conductivity of theoretical porous materials using finite element simulations[J].International Journal of Refrigeration,20038(8):873-880. |
| [38] | 孙爱芳;刘敏珊;董其伍.石墨/PTFE复合材料导热性能的数值模拟[J].材料科学与工程学报,2007(3):430-433. |
| [39] | Yin Y.;Tu ST..Thermal conductivities of PTFE composites with random distributed graphite particles[J].Journal of Reinforced Plastics and Composites,200218(18):1619-1627. |
| [40] | Ramani K.;Vaidyanathan A..FINITE ELEMENT ANALYSIS OF EFFECTIVE THERMAL CONDUCTIVITY OF FILLED POLYMERIC COMPOSITES[J].Journal of Composite Materials,199513(13):1725-1740. |
| [41] | 刘加奇;张立群;杨海波;丁雪佳;陈琪;卢咏来.粒子填充聚合物基复合材料导热性能的数值模拟[J].复合材料学报,2009(1):36-42. |
| [42] | K. Sanada;Y. Tada;Y. Shindo.Thermal conductivity of polymer composites with close-packed structure of nano and micro fillers[J].Composites, Part A. Applied science and manufacturing,20096/7(6/7):724-730. |
| [43] | Dilek Kumlutas;Ismail H. Tavman;M. Turhan Coban.Thermal conductivity of particle filled polyethylene composite materials[J].Composites science and technology,20031(1):113-117. |
| [44] | Lu SY..THE EFFECTIVE THERMAL CONDUCTIVITIES OF COMPOSITES WITH 2-D ARRAYS OF CIRCULAR AND SQUARE CYLINDERS[J].Journal of Composite Materials,19954(4):483-506. |
| [45] | WEN-ZHONG CAI;GUO-LIANG TAG;SHAN-TUNG Tu.Thermal Conductivity of PTFE Composites with Three-dimensional Randomly Distributed Fillers[J].Journal of Thermoplastic Composite Materials,20053(3):241-253. |
| [46] | I.V. Belova;G.E. Murch.Monte Carlo simulation of the effective thermal conductivity in two-phase material[J].Journal of Materials Processing Technology,20040(0):741-745. |
| [47] | 保文星;朱长纯.碳纳米管热传导的分子动力学模拟研究[J].物理学报,2006(7):3552-3557. |
| [48] | Oligschleger C.;Schon JC..Simulation of thermal conductivity and heat transport in solids[J].Physical Review.B.Condensed Matter,19996(6):4125-4133. |
| [49] | 曹杨 .磁性补强三元乙丙橡胶复合材料的制备与性能研究[D].中北大学,2012. |
| [50] | 冯晓利;李志信;过增元.导热系数的分子动力学模拟研究及相关问题的探讨[J].工程热物理学报,2001(2):195-198. |
| [51] | 王宇;王秀喜;倪向贵;吴恒安.单壁碳纳米管轴向压缩变形的研究[J].物理学报,2003(12):3120-3124. |
| [52] | 倪向贵;殷建伟.拉伸条件下双壁碳纳米管弹性性能的原子模拟[J].物理学报,2006(12):6522-6525. |
| [53] | 袁剑辉;程玉民.单壁碳纳米管杨氏模量的掺杂效应[J].物理学报,2007(8):4810-4816. |
| [54] | 袁剑辉;程玉民;张振华.空位结构缺陷对C纳米管弹性性质的影响[J].物理学报,2009(4):2578-2584. |
| [55] | 袁剑辉;程玉民.接枝羧基对单壁碳纳米管弹性性质的影响[J].物理化学学报,2007(6):889-894. |
| [56] | 侯泉文;曹炳阳;过增元.碳纳米管热导率的分子动力学研究[J].工程热物理学报,2009(7):1207-1209. |
| [57] | 杨刚 .碳纳米管/三元乙丙橡胶复合材料导热系数分子动力学模拟[D].青岛科技大学,2013. |
| [58] | 冀英杰 .填充型橡胶复合材料导热性能实验研究及数值模拟[D].青岛科技大学,2013. |
| [59] | Bin YZ.;Kitanaka M.;Zhu D.;Matsuo M..Development of highly oriented polyethylene filled with aligned carbon nanotubes by gelation/crystallization from solutions[J].Macromolecules,200316(16):6213-6219. |
| [60] | 刘琼琼;丛后罗;柳峰;徐冬梅.碳纳米管/橡胶复合材料的制备与性能研究进展[J].合成橡胶工业,2009(4):345-351. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%